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Although modulation of the opioid system has long been central to pain management, the clinical utility of classical MOR agonists is limited by tolerance, dependence, and risk of misuse [132,137]

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A spectrum may therefore contain: Singly charged peptide ions Multiply charged peptide ions Isotope-related peaks Sodium or other adducts Fragment ions Signals from related impurities Signals caused by degradation or analytical conditions The lab should label and explain the spectrum