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Frontiers | Understanding the Emerging Link Between Circadian Rhythm, Nrf2 Pathway, and Breast Cancer to Overcome Drug Resistance

Inhibition of tyrosinase and melanin synthesis Glutathione interferes with the activity of tyrosinase, the rate‑limiting enzyme that converts tyrosine into dopa and dopaquinone, the first steps in melanin production

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While the precise mechanisms remain incompletely understood, these neurons exhibit particular vulnerability to oxidative stress due to their high basal metabolic activity, autonomous pacemaking requiring intense calcium cycling, and ROS generation during dopamine metabolism [187]