glutathione react with sulfenic cysteine kinetically outcompetes reactions between dimedone and a cyclic sulfenamide or physiological acids glutathione synthesis ppt Pathway

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Cox et al

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While the simulations are confined by these assumptions, it is worth noting that redox cycling is governed by thermodynamics, which according to the reduction potential of doxorubicin, are favourable with respect to the formation of superoxide should a semiquinone radical species be present 3